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The primary reason sodium ions are smaller than sodium atoms is that the ion  has only two shells of electrons (the atom has three). Some resources  suggest the ion gets smaller since
The primary reason sodium ions are smaller than sodium atoms is that the ion has only two shells of electrons (the atom has three). Some resources suggest the ion gets smaller since

Why does the K+ ion have a smaller radius than Na+? - Quora
Why does the K+ ion have a smaller radius than Na+? - Quora

Mini-video on ion size (video) | Khan Academy
Mini-video on ion size (video) | Khan Academy

Ionic radius - Wikipedia
Ionic radius - Wikipedia

7.3: Sizes of Atoms and Ions - Chemistry LibreTexts
7.3: Sizes of Atoms and Ions - Chemistry LibreTexts

3.3: Predicting Charges of Ions - Chemistry LibreTexts
3.3: Predicting Charges of Ions - Chemistry LibreTexts

From Lithium‐Ion to Sodium‐Ion Batteries: Advantages, Challenges, and  Surprises - Nayak - 2018 - Angewandte Chemie International Edition - Wiley  Online Library
From Lithium‐Ion to Sodium‐Ion Batteries: Advantages, Challenges, and Surprises - Nayak - 2018 - Angewandte Chemie International Edition - Wiley Online Library

How Comparable Are Sodium-Ion Batteries to Lithium-Ion Counterparts? | ACS  Energy Letters
How Comparable Are Sodium-Ion Batteries to Lithium-Ion Counterparts? | ACS Energy Letters

Why does the Na+ ion have a smaller radius than the Na atom? - Quora
Why does the Na+ ion have a smaller radius than the Na atom? - Quora

Research Development on K-Ion Batteries | Chemical Reviews
Research Development on K-Ion Batteries | Chemical Reviews

Ionic and Atomic Radius - Periodic Trends - YouTube
Ionic and Atomic Radius - Periodic Trends - YouTube

Ions in Solution
Ions in Solution

File:Action potential ion sizes.svg - Wikimedia Commons
File:Action potential ion sizes.svg - Wikimedia Commons

Which ion has the largest radius? "Na"^(+), "Ga"^(3+), "K"^(+), "Mg"^(2+),  "Ca"^(2+) | Socratic
Which ion has the largest radius? "Na"^(+), "Ga"^(3+), "K"^(+), "Mg"^(2+), "Ca"^(2+) | Socratic

Electrode Materials for Sodium-Ion Batteries: Considerations on Crystal  Structures and Sodium Storage Mechanisms | SpringerLink
Electrode Materials for Sodium-Ion Batteries: Considerations on Crystal Structures and Sodium Storage Mechanisms | SpringerLink

High Stability and Long Cycle Life of Rechargeable Sodium-Ion Battery Using  Manganese Oxide Cathode: A Combined Density Functional Theory (DFT) and  Experimental Study | ACS Applied Materials & Interfaces
High Stability and Long Cycle Life of Rechargeable Sodium-Ion Battery Using Manganese Oxide Cathode: A Combined Density Functional Theory (DFT) and Experimental Study | ACS Applied Materials & Interfaces

Frontiers | Hydrated Sodium Ion Clusters [Na+(H2O)n (n = 1–6)]: An ab  initio Study on Structures and Non-covalent Interaction
Frontiers | Hydrated Sodium Ion Clusters [Na+(H2O)n (n = 1–6)]: An ab initio Study on Structures and Non-covalent Interaction

The Role of a Sodium Ion Binding Site in the Allosteric Modulation of the  A2A Adenosine G Protein-Coupled Receptor - ScienceDirect
The Role of a Sodium Ion Binding Site in the Allosteric Modulation of the A2A Adenosine G Protein-Coupled Receptor - ScienceDirect

Measurements of the size and correlations between ions using an  electrolytic point contact | Nature Communications
Measurements of the size and correlations between ions using an electrolytic point contact | Nature Communications

Size does matter | Max Planck Institute for Multidisciplinary Sciences
Size does matter | Max Planck Institute for Multidisciplinary Sciences

Ionic Radius Trends, Basic Introduction, Periodic Table, Sizes of  Isoelectric Ions, Chemistry - YouTube
Ionic Radius Trends, Basic Introduction, Periodic Table, Sizes of Isoelectric Ions, Chemistry - YouTube

Ions in Solution
Ions in Solution

Size of Atoms
Size of Atoms

Why the size of Sodium atom is greater then sodium ion?size of Flourine  atom is smaller then its ion - YouTube
Why the size of Sodium atom is greater then sodium ion?size of Flourine atom is smaller then its ion - YouTube

Media Portfolio
Media Portfolio

Towards K‐Ion and Na‐Ion Batteries as “Beyond Li‐Ion” - Kubota - 2018 - The  Chemical Record - Wiley Online Library
Towards K‐Ion and Na‐Ion Batteries as “Beyond Li‐Ion” - Kubota - 2018 - The Chemical Record - Wiley Online Library

Periodicity: 5.22 - Ionic radius
Periodicity: 5.22 - Ionic radius